Preparation, Characterisation and Catalytic Behaviour of a New TeVMoO Crystalline Phase

TeM_xMo_1.7O mixed oxides (M = V and/or Nb; x = 0-1.7) have been prepared by calcination of the corresponding salts at 600 °C in an atmosphere of N₂. A new crystalline phase, with a Te/V/Mo atomic ratio of 1/0.2-1.5/1.7, has been isolated and characterised by XRD and IR spectroscopy. This phase is observed in the TeVMo or TeVNbMo mixed oxide but not in the TeNbMo mixed oxide. The new crystalline phase shows an XRD pattern similar to Sb₄Mo₁₀O₃₁ and probably corresponds to the M1 phase recently proposed by Aouine et al. (Chem. Commun. 1180, 2001) to be present in the active and selective MoVTeNbO catalysts. Although these catalysts present a very low activity in the propane oxidation, they are active and selective in the oxidation of propene to acrolein and/or acrylic acid. However, the product distribution depends on the catalyst composition. Acrolein or acrylic acid can be selectively obtained from propene on Nb-free or Nb-containing TeVMo catalysts, respectively. The presence of both V and Nb, in addition to Mo and Te, appears to be important in the formation of acrylic acid from propene.     

十二酰胺丙基二甲基羟乙基氯化铵与十二烷基硫酸钠水溶液的表面吸附和胶束形成

利用十二酰胺丙基二甲胺和氯乙醇反应 ,合成了十二酰胺丙基二甲基羟乙基氯化铵 (DDHA)阳离子表面活性剂 ,将其与十二烷基硫酸钠 (SDS)以不同摩尔比进行混合 ,测定了混合系统的表面张力 ,计算了单一系统和混合系统的饱和吸附量、分子最小截面积 ,表面层和胶束中 DDHA的摩尔分率及分子间相互作用参数 ,目视观察了混合系统的浑浊情况。结果表明 :在降低γcmc和 cmc方面 ,DDHA SDS混合系统有协同效应 ,表面层和胶束的组成与二组分配比有关 ,但是非对称的 ,等物质的量混合物中 ,DDHA在胶束和表面层中具有较大的摩尔分数。DDHA与 SDS在实验测定的各混合系统中都不出现混浊     

深层搅拌水泥桩复合地基在工程中的应用

简要介绍了深层搅拌水泥桩的加固机理和适用条件。详细阐述了深层搅拌水泥桩的加固设计，其内容包括布桩形式，单桩竖向承载力及复合地基承载力的确定以及下卧层与沉降变形的验算。指出了施工中应注意的事项和应通过的质量检验项目，并通过工程实例进行了验证。     

Synthesis, Characterization and Crystal Structure of Quaternary Complex of Gadolinium （Ⅲ）

Ａｎｕｍｂｅｒｏｆｌａｎｔｈａｎｉｄｅｔｅｒｎａｒｙｃｏｍｐｌｅｘｅｓｃｏｎ ｔａｉｎｉｎｇｈｅｔｅｒｏｃｙｃｌｉｃａｍｉｎｅｓｈａｖｅｂｅｅｎｒｅｐｏｒｔｅｄｓｉｎｃｅ1960 [1] .Ｉｎｒｅｃｅｎｔｙｅａｒｓｍｕｃｈａｔｔｅｎｔｉｏｎｈａｓｂｅｅｎｐａｉｄｔｏｑｕａｔｅｒｎａｒｙｃｏｍｐｌｅｘｅｓｏｆｌａｎｔｈａｎｉｄｅｓｂｅｃａｕｓｅｏｆｉｎ ｔｅｒｅｓｔｉｎｇｓｔｒｕｃｔｕｒｅ ,ｃｏｏｒｄｉｎａｔｉｏｎｍｏｄｅ ,ｃｏｍｐｅｔｉｔｉｏｎｒｅ ａｃｔｉｏｎａｎｄｐｒｏｐｅｒｔｙ[2～ 9] .ＥＳＲｃａｎｅ…     

胡状集油田胡5-15井区天然混合羧酸盐/黄胞胶驱油先导试验

报道了在室内实验研究中得到的混合天然羧酸盐/烷基磺基甜菜碱/黄胞胶复合驱油段塞结构:预冲洗段塞,10g/LKCl溶液;前置聚合物段塞,1500mg/L黄胞胶溶液;主驱油段塞,1.5×104mg/L混合天然羧酸盐+800mg/L烷基磺基甜菜碱DSB+800mg/L黄胞胶+5×103mg/L复碱(质量比1∶1的Na2CO3+NaHCO3)溶液;后置聚合物段塞,1000mg/L黄胞胶溶液。在岩心流动实验中0.3PV主段塞在水驱基础上提高采收率18.19%。胡状集油田胡5 15井区采出程度18.48%,油藏温度86℃,地层水矿化度1.7×105mg/L,Ca2+浓度4799mg/L,Mg2+浓度830mg/L,有油、水井各5口,综合含水已达96%(92%～99%)。从2000 01 24到2001 03 20,在5口注水井中依次注入预冲洗液2920m3,前置液2920m3,主驱油液49640m3(除一口井外均不加复碱),后置液2920m3,5口油井均见效,一些油井有效期超过20个月,油井产油量增加,含水下降,自然递减降低62.7%,采油速度升高0.46%。图3表2参3。     

国外富过磷酸钙生产技术动态

本文介绍了国外富过磷酸钙生产技术的新进展。讨论了富过酸钙在我国的发展前景。     

哈尔滨炼油厂MTBE装置试生产

介绍了哈尔滨炼油厂ＭＴＢＥ装置的工艺路线、新技术的应用及特点；催化剂的装填及应用情况；总结了生产过程中遇到的一系列问题及解决办法；探索了平稳生产的新徐径，以保证装置安全、平稳、长周期运行；同时对反应器操作温度、催化蒸馏塔操作压力、原料中醇烯比等因素对异丁烯转化率及ＭＴＢＥ产品的影响做了简单的总结。     

Measurements of Stress Intensity Factors of an Interface Crack Under Mixed Mode Loading

The optical method of caustics has been utilised to measure both the stress intensity factor for a crack lying along the interface of an aluminium/epoxy bimaterial specimen, and the mode mixity arising from the difference in the elastic properties across the interface. Measurements were carried out by using a novel modification to the method whereby caustics are produced and measured from both sides of the specimen, so compensating automatically for the distortion induced in the specimen due to misaligned loading fixtures. A flat reflective surface across the interface was obtained by adhering a reflective coating to the specimen. Verification that this coating does not affect measurement accuracy was obtained by comparing stress intensity factors measured from coated and uncoated monolithic aluminium specimens where good agreement was found to exist between both measurements.     

Calculation of second virial coefficients and gaseous viscosities of the refrigerants HFC-32 (CH2 F2), HFC-23 (CHF3), and HCFC-22 (CHC1F2)

The second virial coefficients of refrigerants HFC-32 (CH₂F₂), HFC-23 (CHF₃), and HCFC-22 (CHC1F₂) have been correlated on the bisis of site site model potential and have been compared with experimental results. The molecular interactions consisted of repulsion dispersion and electrostatic parts. From the site site potentials adjusted to the experimental second virial coefficients, spherically averaged potentials have been determined and a subsequent calculation of gaseous viscosity has been carried out. Agreement between measured and calculated values of second virial coellicients and gaseous viscosity is satisfactory. Calculated values of second virial coefficients and gaseous viscosity beyond available experimental data, therefore. can be assumed as a reliable extrapolation to lower and higher temperatures.